Gold supported on a mesoporous CeO2 matrix as an efficient catalyst in the selective aerobic oxidation of aldehydes in the liquid phase

被引:127
作者
Corma, A [1 ]
Domine, ME [1 ]
机构
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
关键词
D O I
10.1039/b506685a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Gold supported on CeO2 catalyses the selective aerobic oxidation of aliphatic and aromatic aldehydes better than other reported catalysts such as Pt/C/Bi materials; the activity is due to the nanometric particle size of Au and CeO2.
引用
收藏
页码:4042 / 4044
页数:3
相关论文
共 20 条
  • [1] Low-temperature water-gas shift reaction on Au/alpha-Fe2O3 catalyst
    Andreeva, D
    Idakiev, V
    Tabakova, T
    Andreev, A
    Giovanoli, R
    [J]. APPLIED CATALYSIS A-GENERAL, 1996, 134 (02) : 275 - 283
  • [2] ANELLI PL, 1987, J ORG CHEM, V52, P2559
  • [3] The role of the metal during NO2 reduction by C3H6 over alumina and silica-supported catalysts
    Bamwenda, GR
    Obuchi, A
    Ogata, A
    Oi, J
    Kushiyama, S
    Mizuno, K
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 126 (2-3) : 151 - 159
  • [4] Selective oxidation of alcohols and aldehydes on metal catalysts
    Besson, M
    Gallezot, P
    [J]. CATALYSIS TODAY, 2000, 57 (1-2) : 127 - 141
  • [5] Gold catalyzed oxidation of aldehydes in liquid phase
    Biella, S
    Prati, L
    Rossi, M
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 197 (1-2) : 207 - 212
  • [6] Bond G.C., 1973, Gold Bulletin, V6, P102, DOI [DOI 10.1007/BF03215018, 10.1007/BF03215018]
  • [7] Supported gold catalyzes the homocoupling of phenylboronic acid with high conversion and selectivity
    Carrettin, S
    Guzman, J
    Corma, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (15) : 2242 - 2245
  • [8] Oxidation of glycerol using supported gold catalysts
    Carrettin, S
    McMorn, P
    Johnston, P
    Griffin, K
    Kiely, CJ
    Attard, GA
    Hutchings, GJ
    [J]. TOPICS IN CATALYSIS, 2004, 27 (1-4) : 131 - 136
  • [9] Nanocrystalline CeO2 increases the activity of an for CO oxidation by two orders of magnitude
    Carrettin, S
    Concepción, P
    Corma, A
    Nieto, JML
    Puntes, VF
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (19) : 2538 - 2540
  • [10] A general method for the synthesis of nanostructured large-surface-area materials through the self-assembly of functionalized nanoparticles
    Chane-Ching, JY
    Cobo, F
    Aubert, D
    Harvey, HG
    Airiau, M
    Corma, A
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (03) : 979 - 987