Synthesis of silica nanoparticles having a well-ordered mesostructure using a double surfactant system

被引:339
作者
Suzuki, K [1 ]
Ikari, K [1 ]
Imai, H [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Yokohama, Kanagawa 2238522, Japan
关键词
D O I
10.1021/ja038250d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A well-ordered hexagonal structure of the mesopores was produced by previous hydrolysis of tetraethoxysilane with hydrochloric acid and subsequent assembly of cationic surfactant micelles and anionic silicate species at a basic condition. Mesoporous silica nanoparticles (20-50 nm) having a well-ordered hexagonal mesostructure were produced using a mixture of cationic surfactant as a template and nonionic block copolymer as a suppressant of grain growth. Copyright © 2004 American Chemical Society.
引用
收藏
页码:462 / 463
页数:2
相关论文
共 20 条
[1]   TEMPLATING OF MESOPOROUS MOLECULAR-SIEVES BY NONIONIC POLYETHYLENE OXIDE SURFACTANTS [J].
BAGSHAW, SA ;
PROUZET, E ;
PINNAVAIA, TJ .
SCIENCE, 1995, 269 (5228) :1242-1244
[2]   Tailored syntheses of nanostructured silicas:: Control of particle morphology, particle size and pore size [J].
Büchel, G ;
Grün, M ;
Unger, KK ;
Matsumoto, A ;
Tsutsumi, K .
SUPRAMOLECULAR SCIENCE, 1998, 5 (3-4) :253-259
[3]   Dilute solution routes to various controllable morphologies of MCM-41 silica with a basic medium [J].
Cai, Q ;
Luo, ZS ;
Pang, WQ ;
Fan, YW ;
Chen, XH ;
Cui, FZ .
CHEMISTRY OF MATERIALS, 2001, 13 (02) :258-263
[4]   Synthesis of MCM-48 using mixed cationic-anionic surfactants as templates [J].
Chen, FX ;
Huang, LM ;
Li, QZ .
CHEMISTRY OF MATERIALS, 1997, 9 (12) :2685-+
[5]   Hierarchical porous nanosized organosilicas [J].
El Haskouri, J ;
de Zárate, DO ;
Guillem, C ;
Beltrán-Porter, A ;
Caldés, M ;
Marcos, MD ;
Beltrán-Porter, D ;
Latorre, J ;
Amorós, P .
CHEMISTRY OF MATERIALS, 2002, 14 (11) :4502-4504
[6]  
Fowler CE, 2001, ADV MATER, V13, P649, DOI 10.1002/1521-4095(200105)13:9<649::AID-ADMA649>3.0.CO
[7]  
2-G
[8]   MESOSTRUCTURE DESIGN WITH GEMINI SURFACTANTS - SUPERCAGE FORMATION IN A 3-DIMENSIONAL HEXAGONAL ARRAY [J].
HUO, QS ;
LEON, R ;
PETROFF, PM ;
STUCKY, GD .
SCIENCE, 1995, 268 (5215) :1324-1327
[9]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[10]   Optimum synthesis of mesoporous silica materials from acidic condition [J].
Lin, HP ;
Kuo, CL ;
Wan, BZ ;
Mou, CY .
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2002, 49 (05) :899-906