Investigation of the chemical action of the gliding and "point" arcs between the metallic electrode and aqueous solution

被引:62
作者
Janca, J
Kuzmin, S
Maximov, A
Titova, J
Czernichowski, A
机构
[1] Masaryk Univ, Fac Sci, Dept Phys Elect, CS-61137 Brno, Czech Republic
[2] Russian Acad Sci, Inst Solut Chem, Ivanovo 153460, Russia
[3] Univ Orleans, Dept Phys, F-45067 Orleans, France
关键词
arc; gliding arc; gas temperature; electron temperature; ion composition; ion bombardment; liquid electrode; dye oxidation; kinetics;
D O I
10.1023/A:1021803932496
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The plasma-solution interaction processes for gliding and "point" arcs between the aqueous solution surface and the metal electrode in the gas phase are studied. The plasma, liquid, and surface zones are taken into consideration. The electric field strength is measured, and the gas and electron temperatures and ion composition are estimated for the plasma zone. The cathode fall, water vaporization rate, and active species current yield due to the radiation chemistry mechanism are determined for the surface zone. The efficiency of oxidation of iodine ions and organic dyes by different types of discharge in the liquid zone ape investigated. The difference in action of the various discharge types may be connected with various influences of the plasma and surface zone on the oxidation processes.
引用
收藏
页码:53 / 67
页数:15
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