Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes

被引：362

作者：

Streuff, J ^{[1
]}

Hövelmann, CH ^{[1
]}

Nieger, M ^{[1
]}

Muñiz, K ^{[1
]}

机构：

[1] Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 42期

关键词：

D O I：

10.1021/ja055190y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular diamination reactions are described which yield cyclic ureas as direct products of an oxidative alkene transformation in the presence of palladium acetate and iodosobenzene diacetate as terminal oxidant. The reaction is truly catalytic in metal catalyst and represents the proof of principle for this elusive type of alkene oxidation. Copyright © 2005 American Chemical Society.

引用

页码：14586 / 14587

页数：2

共 42 条

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