Vector parametrization of the N-atom problem in quantum mechanics.: I.: Jacobi vectors

被引：148

作者：

Gatti, F

Lung, C

Menou, M

Justum, Y

Nauts, A

Chapuisat, X

机构：

[1] Univ Montpellier 2, Lab Struct & Dynam Syst Mol & Solides, CNRS, UMR 5636, F-34095 Montpellier 5, France

[2] Univ Paris Sud, Ctr Sci Orsay, Chim Theor Lab, CNRS,URA 0506, F-91405 Orsay, France

[3] Catholic Univ Louvain, Dept Phys, Unite FYAM, B-1348 Louvain, Belgium

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 108卷 / 21期

关键词：

D O I：

10.1063/1.476327

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Within the framework of an adequate spectral representation, the geometrical description of an N-atom molecular system by n = N - 1 Jacobi relative position vectors is shown to be particularly advantageous with regard to the criterion of prediagonalization of the matrix representing the kinetic energy operator. (C) 1998 American Institute of Physics, [S0021-9606(98)02121-7]

引用

页码：8804 / 8820

页数：17

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