Detection of unusual carotenoid esters in fresh mango (Mangifera indica L. cv. 'Kent')

被引:66
作者
Pott, I
Breithaupt, DE
Carle, R
机构
[1] Univ Hohenheim, Inst Food Chem, D-70599 Stuttgart, Germany
[2] Univ Hohenheim, Inst Food Technol, D-70599 Stuttgart, Germany
[3] Univ Hohenheim, Inst Agr Engn Trop & Subtrop, D-70599 Stuttgart, Germany
关键词
mango; Mangifera indica L; carotenoids; carotenoid esters; violaxanthin esters; LC-(APcI)MS;
D O I
10.1016/S0031-9422(03)00466-7
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The carotenoid pattern of mango cv. 'Kent' was investigated by LC-(APcI)MS analyses. In solvent extracts from the mesocarp an unusual carotenoid ester was identified as violaxanthin dibutyrate. For unequivocal identification of butyric acid by an independent method, total lipids were isolated by solvent extraction from the fruit flesh and analyzed by GC after saponification and subsequent methylation. Thus, evidence of butyric acid (1.6 area%) was provided. To the best of our knowledge, this is the first report on a xanthophyll dibutyrate in plants. Additionally, further carotenoid peaks were tentatively assigned to 9-cis-violaxanthin and neochrom or luteoxanthin, respectively, by their UV/vis and NIS data of the saponified extracts. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:825 / 829
页数:5
相关论文
共 19 条
[1]   CHARACTERIZATION OF GLYCOSIDICALLY BOUND AROMA COMPOUNDS IN THE AFRICAN MANGO (MANGIFERA-INDICA L) [J].
ADEDEJI, J ;
HARTMAN, TG ;
LECH, J ;
HO, CT .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1992, 40 (04) :659-661
[2]  
[Anonymous], 1995, PRODUCTION EC FRUITS
[3]  
BAUTISTA E, 1998, REV COL QUIM, V27, P29
[4]   Determination of free and bound carotenoids in paprika (Capsicum annuum L.) by LC/MS [J].
Breithaupt, DE ;
Schwack, W .
EUROPEAN FOOD RESEARCH AND TECHNOLOGY, 2000, 211 (01) :52-55
[5]   Carotenoids and carotenoid esters in potatoes (Solanum tuberosum L.):: New insights into an ancient vegetable [J].
Breithaupt, DE ;
Bamedi, A .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (24) :7175-7181
[6]   Differentiation between lutein monoester regioisomers and detection of lutein diesters from marigold flowers (Tagetes erecta L.) and several fruits by liquid chromatography-mass Spectrometry [J].
Breithaupt, DE ;
Wirt, U ;
Bamedi, A .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (01) :66-70
[7]  
Breithaupt DE, 2000, Z NATURFORSCH C, V55, P971
[8]   CAROTENOID AND CAROTENOID ESTER COMPOSITION IN MANGO FRUIT AS INFLUENCED BY PROCESSING METHOD [J].
CANO, MP ;
DEANCOS, B .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1994, 42 (12) :2737-2742
[9]  
GODOY HT, 1989, LEBENSM WISS TECHNOL, V22, P100
[10]  
KOST HP, 1988, CRC HDB CHROMATOGRAP, V1