Polyfurfuryl alcohol composite as adsorbent of polychlorinated biphenyls and pyrethroid insecticides

被引：5

作者：

A. Esteve-Turrillas, Francesc

Perez-Cabero, Monica

de la C. Garcia, Teresita

Zahedi, Shahla

Pastor, Agustin

Martinez, Ricardo ^{[1
]}

机构：

[1] Univ Havana, IMRE, Polymer Lab, Havana 10400, Cuba

[2] Univ Valencia, Dept Analyt Chem, E-46100 Valencia, Spain

[3] Univ Valencia, Inst Ciencia Mat, Valencia 46071, Spain

[4] Agrary Univ Havana, Dept Chem, Havana 32700, Cuba

来源：

POLYMER TESTING | 2007年 / 26卷 / 05期

关键词：

furfuryl alcohol; silica composite; environment pollutant samplers; PCB; pyrethroid;

D O I：

10.1016/j.polymertesting.2007.02.006

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Composites from furfuryl alcohol and silica gel were prepared in dichloromethane using trifluoroacetic acid as catalyst and characterized by means of thermogravimetric analysis, transmission electron microscopy and nitrogen adsorption-desorption isotherms. The polymer content in the composites ranged between 19.5% and 32.9%. The capability to adsorb polychlorinated biphenyls and pyrethroid insecticides was tested for composite samples containing different percentages of polymer. Pyrethroids are retained almost totally by composites containing around 24-33% of polymer, while recovery of PCBs close to 80% is obtained with all the composites. No selectivity between compounds of the same family was observed. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：587 / 594

页数：8

共 15 条

[1] Occurrence and determination of pesticides in natural and treated waters
Biziuk, M
Przyjazny, A
Czerwinski, J
Wiergowski, M
[J]. JOURNAL OF CHROMATOGRAPHY A, 1996, 754 (1-2) : 103 - 123
[2] Acid-catalyzed polycondensation of furfuryl alcohol: Mechanisms of chromophore formation and cross-linking
Choura, M
Belgacem, NM
Gandini, A
[J]. MACROMOLECULES, 1996, 29 (11) : 3839 - 3850
[3] Determination of pyrethroid insecticide residues in vegetable oils by using combined solid-phases extraction and tandem mass spectrometry detection
Esteve-Turrillas, FA
Pastor, A
de la Guardia, M
[J]. ANALYTICA CHIMICA ACTA, 2005, 553 (1-2) : 50 - 57
[4] Furans in polymer chemistry
Gandini, A
Belgacem, MN
[J]. PROGRESS IN POLYMER SCIENCE, 1997, 22 (06) : 1203 - 1379
[5] Study by thermal analysis of composites prepared from silica gel, furfuryl alcohol and acetaldehyde
García, TD
Gómez, MR
Martínez, R
Alonso, C
[J]. POLYMER INTERNATIONAL, 2003, 52 (01) : 86 - 91
[6] GONZALEZ R, 1992, MAKROMOL CHEM, V193, P1
[7] Hatrik S, 1996, J CHROMATOGR A, V733, P217
[8] PRINCIPE M, 2003, THESIS HABANA
[9] Composites prepared from silica gel and furfuryl alcohol with p-toluenesulfphonic acid as the catalyst
Principe, Martha
Suarez, Heidi
Jimenez, Guillermo H.
Martinez, Ricardo
Spange, Stefan
[J]. POLYMER BULLETIN, 2007, 58 (04) : 619 - 626
[10] SPANGE S, 1992, MAKROMOL CHEM-RAPID, V13, P511

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