Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks

被引:8
作者
Burke, NJ [1 ]
Burrows, AD [1 ]
Mahon, MF [1 ]
Pritchard, LS [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源
CRYSTENGCOMM | 2003年 / 5卷
关键词
D O I
10.1039/b309884b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structures of two hydrogen-bonded adducts containing omicron-bromoterephthalate have been determined and shown to be virtually identical to those of their terephthalate analogues. Consequently, the strategy of manipulating the relative orientation of the carboxylate groups by adding a bromine atom to terephthalate, which has previously been used to give metal-organic frameworks with predictable structure, can be frustrated with the observation of disorder in the bromine position.
引用
收藏
页码:355 / 357
页数:3
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