The thermal behaviour of nickel, copper and zinc complexes with the Schiff bases cis- and trans-N,N′-bis(salicylidene)-1,2-ciclohexadiamine (Salcn)

被引：40

作者：

Cavalheiro, ÉTG ^{[1
]}

Lemos, FCD ^{[1
]}

Schpector, JZ ^{[1
]}

Dockal, ER ^{[1
]}

机构：

[1] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP, Brazil

来源：

THERMOCHIMICA ACTA | 2001年 / 370卷 / 1-2期

基金：

巴西圣保罗研究基金会;

关键词：

nickel; copper; zinc; Schiff bases; thermogravimetry; differential scanning calorimetry;

D O I：

10.1016/S0040-6031(00)00777-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The Schiff base complexes were prepared and characterised by UV, IR and NMR (H-1 and C-13) spectroscopy, elemental analysis and X-ray powder diffractometry. Free ligands and some new complexes were submitted to thermal analysis (TG and DSC) under dynamic air atmosphere. The differences in the decomposition profiles were related to the structure of isomers and decomposition intermediates were characterised according to their X-ray diffraction pattern. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：129 / 133

页数：5

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