Oxygen atom transfer from a chiral N-alkyl oxaziridine promoted by acid.: The asymmetric oxidation of sulfides to sulfoxides.

被引：50

作者：

Bohé, L ^{[1
]}

Lusinchi, M ^{[1
]}

Lusinchi, X ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France

来源：

TETRAHEDRON | 1999年 / 55卷 / 01期

关键词：

D O I：

10.1016/S0040-4020(98)01035-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral N-alkyl oxaziridines may be used as reagents for the asymmetric oxidation of sulfides in an acid-promoted reaction leading exclusively to the corresponding sulfoxides A planar transition state geometry seems consistent with the observed stereochemistry which should result from the steric interactions in the transition state. The influence of the solvent and the acid strength on the oxygen transfer reaction are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：155 / 166

页数：12

共 29 条

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