Changes in various physical/chemical parameters of Pinus pinaster wood after steam explosion pretreatment

被引:148
作者
Negro, MJ [1 ]
Manzanares, P [1 ]
Oliva, JM [1 ]
Ballesteros, I [1 ]
Ballesteros, M [1 ]
机构
[1] Ctr Invest Energet Medioambientales & Tecnol, Dept Energias Renovables, Madrid 28040, Spain
关键词
pretreatment; steam explosion; softwood; chip size; pine;
D O I
10.1016/S0961-9534(03)00017-5
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Steam-explosion process can be satisfactorily used as a pretreatment in ethanol production from lignocellulosic biomass. Traditionally, pretreatment effectiveness is evaluated in terms of hemicellulose solubilization, enzymatic convertibility of cellulose fraction, and recovery of both polysaccharides. In this study some parameters different from composition (main components) have been evaluated as an alternative tool to characterise the effect of steaming pretreatment on lignocellulosic materials. The effect of the most important variables in steam explosion pretreatment (temperature, residence time and chip size) on various physical/chemical parameters of pine biomass were investigated. Changes in O/C and H/C atomic ratios, colour analysis, elementary composition, water drop penetration time, organic soluble content, cellulose cristallinity index, and thermogravimetric analysis after the pretreatment were evaluated. Furthermore the influence of operational pretreatment variables on all such parameters and their interactions were examined with the Yates' algorithm. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:301 / 308
页数:8
相关论文
共 26 条
[1]   Effect of chip size on steam explosion pretreatment of softwood [J].
Ballesteros, I ;
Oliva, JM ;
Navarro, AA ;
González, A ;
Carrasco, J ;
Ballesteros, M .
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 2000, 84-6 (1-9) :97-110
[2]  
CARRASCO J, 1989, BIOMASS ENERGY IND, P38
[3]   CHARACTERIZATION OF AUTOHYDROLYSIS ASPEN (POPULUS-TREMULOIDES) LIGNINS .1. COMPOSITION AND MOLECULAR-WEIGHT DISTRIBUTION OF EXTRACTED AUTOHYDROLYSIS LIGNIN [J].
CHUA, MGS ;
WAYMAN, M .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (10) :1141-1149
[4]   STEAM EXPLOSION OF THE SOFTWOOD PINUS-RADIATA WITH SULFUR-DIOXIDE ADDITION .1. PROCESS OPTIMIZATION [J].
CLARK, TA ;
MACKIE, KL .
JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 1987, 7 (03) :373-403
[5]   Transformation of wheat straw in the course of solid-state fermentation by four ligninolytic basidiomycetes [J].
Dorado, J ;
Almendros, G ;
Camarero, S ;
Martínez, AT ;
Vares, T ;
Hatakka, A .
ENZYME AND MICROBIAL TECHNOLOGY, 1999, 25 (07) :605-612
[6]   Bioconversion of forest products industry waste cellulosics to fuel ethanol: A review [J].
Duff, SJB ;
Murray, WD .
BIORESOURCE TECHNOLOGY, 1996, 55 (01) :1-33
[7]  
EFFLAND MJ, 1977, TAPPI, V60, P143
[8]   SACCHARIFICATION OF STEAM-EXPLODED POPLAR WOOD [J].
EXCOFFIER, G ;
TOUSSAINT, B ;
VIGNON, MR .
BIOTECHNOLOGY AND BIOENGINEERING, 1991, 38 (11) :1308-1317
[9]  
FEIST WC, 1984, ADV CHEM SER, P401
[10]   Thermal analysis of biomass and corresponding pyrolysis products [J].
Ghetti, P ;
Ricca, L ;
Angelini, L .
FUEL, 1996, 75 (05) :565-573