Reactive dicarbonyl compounds and 5-(hydroxymethyl)-2-furfural in carbonated beverages containing high fructose corn syrup

被引:68
作者
Lo, Chih-Yu [1 ,2 ]
Li, Shiming [2 ]
Wang, Yu [2 ]
Tan, Di [2 ]
Pan, Min-Hsiung [3 ]
Sang, Shengmin [4 ]
Ho, Chi-Tang [2 ,5 ]
机构
[1] Natl Chiayi Univ, Dept Food Sci, Chiayi 600, Taiwan
[2] Rutgers State Univ, Dept Food Sci, New Brunswick, NJ 08901 USA
[3] Natl Kaohsiung Marine Univ, Dept Seafood Sci, Kaohsiung 811, Taiwan
[4] Rutgers State Univ, Ernest Mario Sch Pharm, Dept Biol Chem, Piscataway, NJ 08854 USA
[5] Natl Taiwan Univ, Grad Inst Food Sci & Technol, Taipei 106, Taiwan
关键词
alpha-dicarbonyl compounds; carbonated soft drink; high fructose corn syrup; glyoxal; methylglyoxal; 3-deoxyglucosone; 5-(hydroxymethyl)-2-furfural;
D O I
10.1016/j.foodchem.2007.09.028
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
alpha-Dicarbonyl compounds, namely glyoxal (GO), methylglyoxal (MGO) and 3-deoxyglucosone (3-DOG), as well as 5-(hydroxymethyl)-2-furfural (5-HMF) were found and measured in carbonated soft drinks (CSD). It was realized that high fructose corn syrup (HFCS) in regular CSI)s was the major source of alpha-dicarbonyl compounds in beverages after comparison of levels in regular and diet CSDs. In two most commonly used HFCS formulas, 42% and 55% HFCS, the highest level of dicarbonyl found was 3-DOG, followed by MGO, and then GO. The stability of dicarbonyls in CSDs containing HFCS and (-)-epigallocatechin gallate (EGCG) which were incubated at 35 and 45 degrees C was investigated. It was found that EGCG decreased from I mg/mL to 0.5 and 0.3 mg/mL for 35 and 45 degrees C, respectively, in 16 days storage. Moreover, the reactions of EGCG with MGO, 3-DOG and 5-HMF were observed from the comparison of storage CSDs with and without EGCG under acidic conditions. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1099 / 1105
页数:7
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