Asymmetric hetero Diels-Alder reactions of Danishefsky's diene and glyoxylate esters catalyzed by chiral bisoxazoline derived catalysts

被引：78

作者：

Ghosh, AK

Packiarajan, M

Cappiello, J

Krishnan, K

机构：

[1] Department of Chemistry, University of Illinois at Chicago, Chicago, IL 60607

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 08期

关键词：

D O I：

10.1016/0957-4166(96)00261-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric hetero Diels-Alder reactions of Danishefsky's diene and glyoxylate esters catalyzed by bis(oxazoline)-metal complex afforded the corresponding aldol adduct which upon treatment with trifluoroacetic acid furnished the hetero Diels-Alder product in 72% enantiomeric excess and 70% isolated yield. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2165 / 2168

页数：4

共 36 条

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