Supramolecular construction of molecular ladders in the solid state

被引：260

作者：

Gao, XC ^{[1
]}

Friscic, T ^{[1
]}

MacGillivray, LR ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 02期

关键词：

dimerization; ladderanes; self-assembly; supramolecular chemistry; topochemistry;

D O I：

10.1002/anie.200352713

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Steps in supramolecular chemistry: Molecules in the form of linear templates have been used to preorganize polyenes in the solid state through hydrogen-bonding interactions. The polyenes can then undergo [2+2] photocycloaddition reactions to produce [3]- and [5]ladderanes in gram quantities and 100% yield. (The picture shows the obtained [5]ladderane.).

引用

页码：232 / 236

页数：5

共 52 条

[1] PHOTO-POLYMERIZATION IN CHIRAL CRYSTALS .1. PLANNING AND EXECUTION OF A TOPOCHEMICAL SOLID-STATE ASYMMETRIC SYNTHESIS WITH QUANTITATIVE ASYMMETRIC INDUCTION [J].