Schiff bases of increasing complexity as mild steel corrosion inhibitors in 2 M HCl

被引:101
作者
Kustu, Canan [1 ]
Emregul, Kaan C. [1 ]
Atakol, Orhan [1 ]
机构
[1] Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey
关键词
mild steel; EIS; polarization; acid inhibition;
D O I
10.1016/j.corsci.2007.02.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of three Schiff base compounds with increasing number of coordination sites, namely, 2-{(E)-[(2-hydroxyethyl)imino]methyl} phenol (1), 2-[(E)-({2-[(2-hydroxyethyl) amino]ethyl}imino) methyl]phenol (II) and 2,2'-{iminobis[ethane-2,1-diylnitrilo(E)methylylidene]}diphenol (III) have been investigated at 298 K by weight loss measurements, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The inhibition efficiencies obtained from all methods employed are in good agreement. Results show compound III to be the best inhibitor with a mean efficiency of 93% at 10(-2) M additive concentration. Studies showed all three compounds to act as mixed type inhibitors. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2800 / 2814
页数:15
相关论文
共 27 条
[1]   Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304 stainless steel in hydrochloric acid solution [J].
Abdallah, M .
CORROSION SCIENCE, 2002, 44 (04) :717-728
[2]  
[Anonymous], 1979, CORROSION CONTROL CO
[3]   A new triazole derivative as inhibitor of the acid corrosion of mild steel:: electrochemical studies, weight loss determination, SEM and XPS [J].
Bentiss, F ;
Traisnel, M ;
Gengembre, L ;
Lagrenée, M .
APPLIED SURFACE SCIENCE, 1999, 152 (3-4) :237-249
[4]   The corrosion inhibition of mild steel in acidic media by a new triazole derivative [J].
Bentiss, F ;
Lagrenee, M ;
Traisnel, M ;
Hornez, JC .
CORROSION SCIENCE, 1999, 41 (04) :789-803
[5]   ELECTROCHEMICAL-BEHAVIOR OF COPPER IN 0.5-M H2SO4 SOLUTIONS IN THE ABSENCE AND PRESENCE OF FE(III) AND BENZOTRIAZOLE [J].
DACOSTA, SLFA ;
AGOSTINHO, SML .
CORROSION, 1989, 45 (06) :472-477
[6]   SCHIFF-BASES AS CORROSION-INHIBITORS FOR MILD-STEEL IN HYDROCHLORIC-ACID SOLUTIONS [J].
DESAI, MN ;
DESAI, MB ;
SHAH, CB ;
DESAI, SM .
CORROSION SCIENCE, 1986, 26 (10) :827-837
[7]   Synthesis of some cationic gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid medium [J].
El Achouri, M ;
Infante, MR ;
Izquierdo, F ;
Kertit, S ;
Gouttaya, HM ;
Nciri, B .
CORROSION SCIENCE, 2001, 43 (01) :19-35
[8]  
ELAWADY YA, 1985, INDIAN J CHEM A, V24, P601
[9]   Corrosion inhibition of mild steel with Schiff base compounds in 1 M HCl [J].
Emregül, KC ;
Atakol, O .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 82 (01) :188-193
[10]   An investigation of chloride-substituted Schiff bases as corrosion inhibitors for steel [J].
Emregül, Kaan C. ;
Kurtaran, Raif ;
Atakol, Orhan .
Corrosion Science, 2003, 45 (12) :2803-2817