Synthesis and structure of a novel tetranuclear tungsten-bismuth-sulfur complex

被引：6

作者：

Li, HX

Xu, QF

Shen, Q

Lang, JP

机构：

[1] Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 07期

关键词：

D O I：

10.1246/cl.2003.642

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [PPh4](2)[WS4] with 1/3 equiv. of BiCl3 in CH2Cl2 afforded a new W/Bi/S complex [PPh4](3)[Bi(WS4)(3)] (1). The structure of the trianion of 1 represents the first example of W/Bi/S complex which contains a central Bi coordinated by six S atoms of the three [WS4](2-) moieties.

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页码：642 / 643

页数：2

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