Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

被引：58

作者：

Blay, G

Fernández, I

Giménez, T

Pedro, JR ^{[1
]}

Ruiz, R

Pardo, E

Lloret, F

Muñoz, MC

机构：

[1] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Burjassot, Spain

[2] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Burjassot, Spain

[3] Univ Politecn Valencia, Dept Fis Aplicada, E-46071 Valencia, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 20期

关键词：

D O I：

10.1039/b105132f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new manganese( III) oxamato dimer possesing an unprecedented Mn-2(mu -O2CR)(mu -OH2. . .O2CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by (BuO2H)-O-t and O-2 in CH2Cl2 at rt.

引用

页码：2102 / 2103

页数：2

共 19 条

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