Poly(disulfide)s

被引:188
作者
Bang, Eun-Kyoung [1 ]
Lista, Marco [1 ]
Sforazzini, Giuseppe [1 ]
Sakai, Naomi [1 ]
Matile, Stefan [1 ]
机构
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland
基金
欧洲研究理事会;
关键词
POLYMERIZED DEPOLYMERIZED VESICLES; CONJUGATED BIOREDUCIBLE POLYMER; AROMATIC DISULFIDE OLIGOMERS; POLY(AMIDO AMINE)S; GENE DELIVERY; LIPOIC ACID; ONCOLYTIC ADENOVIRUS; COVALENT CAPTURE; CYCLIC DISULFIDE; DEGRADATION;
D O I
10.1039/c2sc20098h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Don't forget poly(disulfide)s. There is a rich literature pointing out the advantages of the dynamic nature of single disulfide bridges to explore self-sorting, biomolecular engineering, biomembrane analysis, and so on. Disulfide bonds between polymer chains are essential for protein folding, materials properties and the stabilization of various supramolecular architectures. However, poly(disulfide) s with disulfide bonds in the main chain are rarely used today to create interesting structures or functions. To attract attention and outline scope and limitations of poly(disulfide) s to build modern supramolecular systems, the rather eclectic recent literature on the topic is summarized. The review is moving from fascinating basic studies including photoinduced metathesis, polycatenanes and polyrotaxanes to applications in biosupramolecular systems such as micelles, membranes, tubes, gels, carriers, pores, sensors, catalysts and photosystems.
引用
收藏
页码:1752 / 1763
页数:12
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