Chiral phosphine-phosphonium ylide rhodium complexes

被引：35

作者：

Viau, L ^{[1
]}

Lepetit, C ^{[1
]}

Commenges, G ^{[1
]}

Chauvin, R ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 05期

关键词：

D O I：

10.1021/om000885n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phosphonium methylide of (R)-BINAP acts as a novel chiral dissymmetric chelating ligand in the stable [Rh(cod)(BINAPCH(2))](+) complex. A rationale for the conformation of the eight-membered metallacycle derived from chiral phosphine-phosphonium ylide ligands is proposed on the basis of DFT calculations on a model complex.

引用

收藏

页码：808 / 810

页数：3

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