Rational design of sequestering agents for plutonium and other actinides

被引:508
作者
Gorden, AEV
Xu, JD
Raymond, KN [1 ]
Durbin, P
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA
关键词
D O I
10.1021/cr990114x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An overview is given of a research which is the result of many years of collaborative effort in inorganic chemistry, synthetic organic chemistry, and actinide biology. This collaboration has advanced areas of nutritional science, clinical medicine, and radiation protection. Each of these areas will benefit from further studies in this field and the development of new and improved ligands for the treatment of actinide poisoning, whether from accidents or weapons use. Focus is on the most common actinides and those deemed most likely to be present in nuclear fuel and wastes, namely plutonium, thorium, americium, uranium, and neptunium.
引用
收藏
页码:4207 / 4282
页数:76
相关论文
共 475 条
[1]   SPECIFIC SEQUESTERING AGENTS FOR THE ACTINIDES .8. SYNTHESIS AND STRUCTURAL CHEMISTRY OF TETRAKIS(THIOHYDROXAMATO)HAFNIUM(IV) IN HF(CH3C6H4(S)N(O)CH3)4.C2H5OH [J].
ABUDARI, K ;
RAYMOND, KN .
INORGANIC CHEMISTRY, 1982, 21 (04) :1676-1679
[2]   A NOTE ON AMN AND AMO [J].
AKIMOTO, Y .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1967, 29 (10) :2650-&
[3]  
Albright D., 1997, Plutonium and Highly Enriched Uranium 1996: World Inventories, Capabilities, and Policies
[4]   ENVIRONMENTAL ACTINIDE CHEMISTRY [J].
ALLARD, B ;
OLOFSSON, U ;
TORSTENFELT, B .
INORGANICA CHIMICA ACTA-F-BLOCK ELEMENTS ARTICLES AND LETTERS, 1984, 94 (04) :205-221
[5]   EXAFS determinations of uranium structures: The uranyl ion complexed with tartaric, citric, and malic acids [J].
Allen, PG ;
Shuh, DK ;
Bucher, JJ ;
Edelstein, NM ;
Reich, T ;
Denecke, MA ;
Nitsche, H .
INORGANIC CHEMISTRY, 1996, 35 (03) :784-+
[6]   Coordination chemistry of trivalent lanthanide and actinide ions in dilute and concentrated chloride solutions [J].
Allen, PG ;
Bucher, JJ ;
Shuh, DK ;
Edelstein, NM ;
Craig, I .
INORGANIC CHEMISTRY, 2000, 39 (03) :595-601
[7]  
[Anonymous], 1995, Ann ICRP, V25, P1
[8]  
[Anonymous], TOXICOLOGY URANIUM
[9]  
[Anonymous], ANN ICRP
[10]  
[Anonymous], 1951, IND MED PLUTONIUM PR