New dioxomolybdenum(VI) complexes of tetradentate Schiff base as catalysts for epoxidation of olefins

被引：85

作者：

Ambroziak, K

Pelech, R

Milchert, E

Dziembowska, T ^{[1
]}

Rozwadowski, Z

机构：

[1] Tech Univ Szczecin, Inst Chem & Environm Protect, Szczecin, Poland

[2] Tech Univ Szczecin, Inst Organ Chem Technol, Szczecin, Poland

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 211卷 / 1-2期

关键词：

epoxidation; dioxomolybdenum(VI) complexes of tetradentate Schiff bases; tert-butyl hydroperoxide;

D O I：

10.1016/j.molcata.2003.09.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Six dioxomolybdenum(VI) complexes of Schiff-bases derivatives of trans-1,2-diaminocyclohexane and R-salicylaldehyde as well as 2-hydroxynaphthaldehyde have been synthesised and characterized by IR, UV-Vis and NMR-spectroscopic methods. The catalytic activities of the complexes in the reaction of epoxidation of cyclohexene and 1-octene with tert-butyl hydroperoxide (TBHP) as oxidant have been studied. (C) 2003 Elsevier B.V. All rights reserved.

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页码：9 / 16

页数：8

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