Fluoride removal by Donnan dialysis with anion exchange membranes

被引:104
作者
Durmaz, F [1 ]
Kara, H [1 ]
Cengeloglu, Y [1 ]
Ersoz, M [1 ]
机构
[1] Selcuk Univ, Dept Chem, TR-42031 Konya, Turkey
关键词
Donnan dialysis; AHA; ion exchange membrane; flux;
D O I
10.1016/j.desal.2004.11.016
中图分类号
TQ [化学工业];
学科分类号
0817 [化学工程与技术];
摘要
The removal of fluoride from diluted solution with Neosepta AHA anion exchange membrane has been studied by Donnan dialysis. The effects of concentration, pH, and accompanying anion on feed phase and receiving phase composition were investigated. Neosepta AHA anion exchange membrane was used for the removal of fluoride and the flux of fluoride with respect to the concentration, pH, and the effect of the counter-ions (HCO3-, Cl-, SO4-2) were obtained between 34-136.10(-7) (m.mol.cm(-2).s(-1)). The effect of the fluoride flux increased with increasing of concentration on the feed phase. The flux of fluoride was found to be higher at higher pH in the feed phase. In addition, the accompanying counter-anions also influenced the flux of fluoride and the order of flux was founded as HCO3-> Cl-> SO4-2. The results obtained for AHA membrane were compared with Neosepta AFN and polysulfone SB-6407 membranes. The transport efficiencies of the membranes were found to be in the order AFN > AHA > SB-6407.
引用
收藏
页码:51 / 57
页数:7
相关论文
共 19 条
[1]
DEFLUORIDATION DURING DESALINATION OF BRACKISH WATER BY ELECTRODIALYSIS [J].
ADHIKARY, SK ;
TIPNIS, UK ;
HARKARE, WP ;
GOVINDAN, KP .
DESALINATION, 1989, 71 (03) :301-312
[2]
[Anonymous], 1995, WATER QUAL RES J, DOI DOI 10.2166/WQRJ.1995.012
[3]
ASARAUX A, 1994, REV RHUMATISME DEC, P847
[4]
BORUFF CS, 1936, IND ENG CHEM, V26, P69
[5]
EFFECTS OF FLUORIDE ON ENAMEL SOLUBILITY AND CARIOSTASIS [J].
BROWN, WE ;
GREGORY, TM ;
CHOW, LC .
CARIES RESEARCH, 1977, 11 :118-136
[6]
BULUSU K R, 1990, Indian Journal of Environmental Health, V32, P197
[7]
Removal of fluoride from aqueous solution by using red mud [J].
Çengeloglu, Y ;
Kir, E ;
Ersöz, M .
SEPARATION AND PURIFICATION TECHNOLOGY, 2002, 28 (01) :81-86
[8]
Recovery and concentration of Al(III), Fe(III), Ti(IV), and Na(I) from red mud [J].
Çengeloglu, Y ;
Kir, E ;
Ersöz, M .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 244 (02) :342-346
[9]
Chaturvedi AK., 1988, APPL CLAY SCI, V3, P337, DOI [10.1016/0169-1317(88)90024-5, DOI 10.1016/0169-1317(88)90024-5]
[10]
Haron M. J., 1995, INT J ENVIRON STUD, V48, P245, DOI DOI 10.1080/00207239508710994