Thermal studies of new Cu(I) and Ag(I) complexes with bipyridine isomers

被引：14

作者：

Czakis-Sulikowska, D ^{[1
]}

Kaluzna, J ^{[1
]}

Radwanska-Doczekalska, J ^{[1
]}

机构：

[1] Lodz Tech Univ, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1998年 / 54卷 / 01期

关键词：

bipyridine isomers; complexes; copper(II); IR spectra; silver(I); thermal decomposition;

D O I：

10.1023/A:1010164818342

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The complexes of the general formula MLSCN (M=Cu(I), Ag(I), L=2,2'-bipyridine=2-bipy, 4,4'-bipyridine=4-bipy or 2,4'-bipyridine=2,4'bipy) have been prepared and their IR spectra examined. The nature of metal-ligand coordination is discussed. Thermal decomposition in air of these complexes occurred in several successive endothermic and exothermic processes and the residue was Cu2O and Ag, respectively.

引用

页码：103 / 113

页数：11

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