Ligand effects in the syntheses of molecular main group metal species containing interstitial hydride

被引：11

作者：

Armstrong, DR

Davies, RP

Clegg, W

Liddle, ST

Linton, DJ

Schooler, P

Snaith, R

Wheatley, AEH

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[3] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 168卷

关键词：

aluminium; 'ate complex; interstitial hydride; lithium; solid-state structure;

D O I：

10.1080/10426500108040539

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In seeking to investigate whether structures of the type observed for {[Me3Al(TMP)]Li}(infinity). (TMP = 2,2,6,6-tetramethylpiperidide) can be oligomerised by the use of polyfunctional N-centred ligands, we report lithium aluminates incorporating RN -C(H)- NR residues. For PhN -C(Ph)- NPh =Am cluster cation-containing (Li4Am3)(+). {Li[(mu -Me)(2)Al(Me)Bu-t](2)](-) is afforded. However, the empolyment of PhN(H)(2-pyr) (pyr = pyridyl) instead affords both [Li-8(H)[N(2-pyr)Ph](6)}(+). [Li(Me2AlBu2t)(2)](-) and Li-7(H)[N(2-pyr)Ph](6): the first molecular Main Group clusters to incorporate interstitial hydride. Results indicate that R-elimination front (BuLi)-Li-t represents the source of H-. in these reactions.

引用

页码：93 / 98

页数：6

共 13 条

[1]

Armstrong DR, 1999, ANGEW CHEM INT EDIT, V38, P3367, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3367::AID-ANIE3367>3.3.CO

[2]

2-L

[3] Towards an understanding of the conjugate addition of organolithium reagents to α,β-unsaturated ketones:: the isolation and solid-state structure of a monomeric lithium aluminate with very short agostic Li•••HC interactions [J].