Studies on mechanism and physico-chemical parameters at the origin of the cement setting .2. Physico-chemical parameters determining the coagulation process

被引:43
作者
Jiang, SP
Mutin, JC
Nonat, A
机构
[1] Lab. Rech. sur Reactiv. des Solides, Université de Bourgogne, Dijon
关键词
D O I
10.1016/S0008-8846(96)85036-8
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The physico-chemical parameters determining the coagulation of cements grains previously identified as the first fundamental process of cement setting have been investigated in diluted suspensions using an adapted granulometric method. The analysis of the influence of the ionic concentration in solution on the coagulation reveals that calcium concentration is the parameter which determines the particle interactions. There exists a minimum critical concentration of calcium ions in solution which is required to occur the coagulation of cement particles and a dispersive effect appears for very high concentrations. The results are discussed in relation with DLVO theory and specific interactions.
引用
收藏
页码:491 / 500
页数:10
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