Synthesis and structure of a one-dimensional coordination polymer based upon tetracyanocalix[4] arene in the cone conformation

被引：10

作者：

Elisabeth, E ^{[1
]}

Barbour, LJ ^{[1
]}

Orr, GW ^{[1
]}

Holman, KT ^{[1
]}

Atwood, JL ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

SUPRAMOLECULAR CHEMISTRY | 2000年 / 12卷 / 03期

关键词：

D O I：

10.1080/10610270008029452

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetracyanocalix[4]arene has been synthesized in a cone formation and crystallized from solution in an orthorhombic system, space group P2(1)2(1)2(1), with a = 13.7999(9) Angstrom, b = 16.820(1) Angstrom, c = 21.787(1) Angstrom, D-c = 1.218 g/cm(3), Z = 4 (C62H47N5O4). Refinement based on 11008 observed reflections yielded R1 = 0.042. Furhter crystallographic studies have revealed that this compound self-assembles into one-dimensional coordination polymer in the presence of Ag+ cation. This extended structure also crystallizes in an orthorhombic system, space group Cmca, with a = 17.770(1) Angstrom, b = 31.498(2) Angstrom, c = 23.107(2) Angstrom, D-c = 1.319 g/cm(3), Z = 8 (C63H52AgCl2F6N4O6P). Refinement based on 7391 observed reflections yielded R1 = 0.109.

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页码：317 / 320

页数：4

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