Aqua(2,2′-bi-1H-imidazole)chlorocopper(II) chloro(iminodiacetato)copper(II) monohydrate

被引：4

作者：

Gao, XL ^{[1
]}

Wei, YB ^{[1
]}

Li, YP ^{[1
]}

Yang, P ^{[1
]}

机构：

[1] Shanxi Univ, Inst Mol Sci Chem Biol & Mol Engn, Lab Educ Minist, Taiyuan 030006, Shanxi, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷

关键词：

D O I：

10.1107/S0108270104028732

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, [CuCl(C6H6N4)(H2O)][Cu(C4H5NO4)Cl] . H2O, the Cu-II atom in the cation is coordinated by one Cl- ion, two N atoms of the 2,2'-biimidazole ligand and one aqua ligand. Within the anion, the Cu (II) atom is bonded to one Cl- ion, and one N and two O atoms of the iminodiacetate ligand. Neighbouring cations and anions are connected to each other by Cu ... Cl semi-coordination bonds of 2.830 ( 12) and 3.071 ( 12) Angstrom, forming a Cu2Cl2 rectangular unit. The dinuclear units further link into a polymeric chain along the a axis through Cu ... O-aqua interactions of 2.725 ( 3) Angstrom. Including the long coordination bonds, the geometries around the Cu atoms in the cation and anion are square-pyramidal and distorted octahedral, respectively.

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页码：M10 / M12

页数：3

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