A one-dimensional zigzag coordination polymer:: {[Ag(2-amino-3-methylpyridine)](ClO4)}∞

被引：6

作者：

Chen, ZF ^{[1
]}

Liu, B

Liang, H

Hu, RX

Zhou, ZY

机构：

[1] Guangxi Normal Univ, Coll Chem & Chem Engn, Guilin 541004, Guangxi, Peoples R China

[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 07期

基金：

美国国家科学基金会;

关键词：

silver(I); coordination polymer; crystal structure;

D O I：

10.1080/00958970500038159

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of silver perchlorate with 2-amino-3-methylpyridine gives a one-dimensional zigzag coordination polymer {[Ag(2-amino-3-methylpyridine)](ClO4)}(infinity) ( 1) consisting of single chains. The geometry of all Ag( I) cations is linear: each ion links together two 2-pyridyl (Ag1) rings and two 2-amino (Ag2) groups, with the ligand exhibiting a 'head-to-head' orientation. Crystal data: monoclinic P2(1)/c, a = 5.2296(8), b = 20.668(3), c = 8.8716(14) angstrom, beta = 100.359(3)degrees, V = 943.3(3) angstrom(3), Z = 2, D-c = 2.214 Mg/m(3), mu = 2.409 mm(-1), F(000) = 612, R1 = 0.0426, wR1 = 0.0980 [I > 2 sigma(I)], S = 0.969.

引用

页码：561 / 565

页数：5

共 21 条

[1]

Abrahams BF, 1998, ANGEW CHEM INT EDIT, V37, P2656, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2656::AID-ANIE2656>3.0.CO

[2]

2-M

[3] Studies of the construction of coordination polymers using linear pyridyl-donor ligands [J].

Batten, SR ;

Jeffery, JC ;

Ward, MD .

INORGANICA CHIMICA ACTA, 1999, 292 (02) :231-237

[4]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[5]

2-Z

[6] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[7]

BOOURAHMA H, 2002, J AM CHEM SOC, V124, P9990

[8] Formation of a single-stranded silver(I) helical-coordination polymer containing π-stacked planar chiral N4S2 ligands [J].

Caradoc-Davies, PL ;

Hanton, LR .

CHEMICAL COMMUNICATIONS, 2001, (12) :1098-1099

[9]

HAFTBARADARAN F, 2003, J CHEM SOC DA, P2105

[10] Supramolecular design of one-dimensional coordination polymers based on silver(I) complexes of aromatic nitrogen-donor ligands [J].

Khlobystov, AN ;

Blake, AJ ;

Champness, NR ;

Lemenovskii, DA ;

Majouga, AG ;

Zyk, NV ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 2001, 222 :155-192

← 1 2 3 →