Framework functionalisation triggers metal complex binding

被引:256
作者
Ingleson, Michael J. [1 ]
Barrio, Jorge Perez [1 ]
Guilbaud, Jean-Baptiste [1 ]
Khimyak, Yaroslav Z. [1 ]
Rosseinsky, Matthew J. [1 ]
机构
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1039/b718367d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Post-synthetic derivatisation of a porous material produces a functionalized material that binds the metal complex V(O)acac(2), in contrast to the unfunctionalized precursor, which is inactive for complex binding.
引用
收藏
页码:2680 / 2682
页数:3
相关论文
共 21 条
  • [1] Molecular dynamics simulation of benzene diffusion in MOF-5: Importance of lattice dynamics
    Amirjalayer, Saeed
    Tafipolsky, Maxim
    Schmid, Rochus
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (03) : 463 - 466
  • [2] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
    Eddaoudi, M
    Kim, J
    Rosi, N
    Vodak, D
    Wachter, J
    O'Keeffe, M
    Yaghi, OM
    [J]. SCIENCE, 2002, 295 (5554) : 469 - 472
  • [3] Crystallized frameworks with giant pores:: Are there limits to the possible?
    Férey, G
    Mellot-Draznieks, C
    Serre, C
    Millange, F
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 217 - 225
  • [4] Investigation of an N•••H hydrogen bond in a solid benzoxazine dimer by 1H-15N NMR correlation techniques under fast magic-angle spinning
    Goward, GR
    Schnell, I
    Brown, SP
    Spiess, HW
    Kim, HD
    Ishida, H
    [J]. MAGNETIC RESONANCE IN CHEMISTRY, 2001, 39 : S5 - S17
  • [5] Gaseous species as reaction tracers in the solvothermal synthesis of the zinc oxide terephthalate MOF-5
    Hausdorf, Steffen
    Baitalow, Felix
    Seidel, Juergen
    Mertens, Florian O. R. L.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (20) : 4259 - 4266
  • [6] Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers
    Heo, Jungseok
    Jeon, You-Moon
    Mirkin, Chad A.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) : 7712 - +
  • [7] Loading of porous metal-organic open frameworks with organometallic CVD precursors:: inclusion compounds of the type [LnM]a@MOF-5
    Hermes, Stephan
    Schroeder, Felicitas
    Amirjalayer, Saeed
    Schmid, Rochus
    Fischer, Roland A.
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (25) : 2464 - 2472
  • [8] Spatial and surface design of porous coordination polymers
    Higuchi, Masakazu
    Horike, Satoshi
    Kitagawa, Susumu
    [J]. SUPRAMOLECULAR CHEMISTRY, 2007, 19 (1-2) : 75 - 78
  • [9] Metal-organic frameworks
    James, SL
    [J]. CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) : 276 - 288
  • [10] Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)
    Kaye, Steven S.
    Dailly, Anne
    Yaghi, Omar M.
    Long, Jeffrey R.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (46) : 14176 - +