Monodisperse bile-salt nanotubes in water: Kinetics of formation

被引：71

作者：

Jean, B

Oss-Ronen, L

Terech, P

Talmon, Y

机构：

[1] Univ Grenoble 1, CNRS, CEA, UMR 5819,Dept Rech Fondamentale Mat Condensee, F-38054 Grenoble, France

[2] European Synchrotron Radiat Facil, F-38043 Grenoble, France

[3] Technion Israel Inst Technol, Dept Chem Engn, IL-32000 Haifa, Israel

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 06期

关键词：

D O I：

10.1002/adma.200401125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sodium lithocholate forms stabilized cylindrical nanotubes with thin monomolecular walls (see Figure) through fast and complex morphological evolutions. The kinetics of formation can be followed by small-angle X-ray scattering using a brilliant synchrotron source, and are corroborated by cryo-transmission electron microscopy. Coaxial cylinders, helical ribbons, fibrils, and single-walled tubes are found to coexist in the first few minutes of the supramolecular organization process.

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页码：728 / +

页数：5

相关论文

共 10 条

[1] Exploiting amyloid fibril lamination for nanotube self-assembly [J].

Lu, K ;

Jacob, J ;

Thiyagarajan, P ;

Conticello, VP ;

Lynn, DG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (21) :6391-6393

[2] OPTICAL MICROSCOPIC STUDY OF HELICAL SUPERSTRUCTURES OF CHIRAL BILAYER-MEMBRANES [J].

NAKASHIMA, N ;

ASAKUMA, S ;

KUNITAKE, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (02) :509-510

[3] SAXS and USAXS on the high brilliance beamline at the ESRF [J].

Narayanan, T ;

Diat, O ;

Bösecke, P .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2001, 467 :1005-1009

[4] Theory of cylindrical tubules and helical ribbons of chiral lipid membranes [J].

Selinger, JV ;

MacKintosh, FC ;

Schnur, JM .

PHYSICAL REVIEW E, 1996, 53 (04) :3804-3818

[5] Theory of self-assembled tubules and helical ribbons [J].

Selinger, JV ;

Spector, MS ;

Schnur, JM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (30) :7157-7169

[6] Chiral self-assembly of nanotubules and ribbons from phospholipid mixtures [J].

Spector, MS ;

Singh, A ;

Messersmith, PB ;

Schnur, JM .

NANO LETTERS, 2001, 1 (07) :375-378

[7]

TALMON Y, 1999, MODERN CHARACTERIZAT, pCH5

[8]

Terech P, 2002, ADV MATER, V14, P495, DOI 10.1002/1521-4095(20020404)14:7<495::AID-ADMA495>3.3.CO

[9]

2-0

[10] Low molecular mass gelators of organic liquids and the properties of their gels [J].

Terech, P ;

Weiss, RG .

CHEMICAL REVIEWS, 1997, 97 (08) :3133-3159