Solid Electrolytes: Applications in Heterogeneous Catalysis and Chemical Cogeneration

被引:43
作者
Garagounis, I.
Kyriakou, V.
Anagnostou, C.
Bourganis, V.
Papachristou, I.
Stoukides, M. [1 ]
机构
[1] Dept Chem Engn, Thessaloniki 54124, Greece
关键词
FARADAIC ELECTROCHEMICAL MODIFICATION; OXIDE FUEL-CELL; YTTRIA-STABILIZED ZIRCONIA; CERAMIC MEMBRANE-REACTOR; WATER-GAS SHIFT; OXYGEN ACTIVITY OSCILLATIONS; PROTON-CONDUCTING MEMBRANE; CARBON-MONOXIDE OXIDATION; SITU CONTROLLED PROMOTION; MONOLITHIC ELECTROPROMOTED REACTOR;
D O I
10.1021/ie1001058
中图分类号
TQ [化学工业];
学科分类号
081705 [工业催化];
摘要
Solid electrolytes have found applications in several areas, including (a) sensors, (b) separators, (c) solid oxide fuel cells, and (d) solid-state batteries. In addition, solid electrolytes have been used in the construction of solid electrolyte cell reactors (SECRs), in which heterogeneous catalytic reactions have been studied. Also, SECRs have been used as chemical cogenerative fuel cells, i.e., for the simultaneous production of electricity and useful compounds. In the present work, a survey of the studies conducted in SECRs is presented. The fundamental operating principles, results in technologically important reactions, and the hurdles that should be overcome to bring SECRs into industrial practice are discussed.
引用
收藏
页码:431 / 472
页数:42
相关论文
共 634 条
[1]
Sulfur-tolerant materials for the hydrogen sulfide SOFC [J].
Aguilar, L ;
Zha, SW ;
Li, SW ;
Winnick, J ;
Liu, M .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (10) :A324-A326
[2]
Kinetics of internal steam reforming of methane on Ni/YSZ-based anodes for solid oxide fuel cells [J].
Ahmed, K ;
Foger, K .
CATALYSIS TODAY, 2000, 63 (2-4) :479-487
[3]
AHN K, 2004, PREPR PAP AM CHEM SO, V49, P755
[4]
Controlled oxidative coupling of methane by ionic conducting ceramic membrane [J].
Akin, FT ;
Lin, YS .
CATALYSIS LETTERS, 2002, 78 (1-4) :239-242
[5]
Selective oxidation of ethane to ethylene in a dense tubular membrane reactor [J].
Akin, FT ;
Lin, YS .
JOURNAL OF MEMBRANE SCIENCE, 2002, 209 (02) :457-467
[6]
Comparative study on oxygen permeation and oxidative coupling of methane on disk-shaped and tubular dense ceramic membrane reactors [J].
Akin, FT ;
Lin, YS ;
Zeng, Y .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (25) :5908-5916
[7]
Fuel cells for chemicals and energy cogeneration [J].
Alcaide, F ;
Cabot, PL ;
Brillas, E .
JOURNAL OF POWER SOURCES, 2006, 153 (01) :47-60
[8]
SYNTHESIS GAS-PRODUCTION FROM METHANE OVER AN IRON ELECTRODE IN A SOLID-ELECTROLYTE CELL [J].
ALQAHTANY, H ;
ENG, D ;
STOUKIDES, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (06) :1677-1681
[9]
ELECTROCATALYTIC DECOMPOSITION OF HYDROGEN-SULFIDE [J].
ALQAHTANY, H ;
CHIANG, PH ;
ENG, D ;
STOUKIDES, M ;
ROBBAT, A .
CATALYSIS LETTERS, 1992, 13 (03) :289-295
[10]
METHANE STEAM REFORMING OVER FE ELECTRODES IN A SOLID-ELECTROLYTE CELL [J].
ALQAHTANY, H ;
ENG, D ;
STOUKIDES, M .
ENERGY & FUELS, 1993, 7 (04) :495-504