Desulfurization yield of calcium hydroxide fly-ash mixtures. Thermogravimetric determination

被引:26
作者
Garea, A [1 ]
Ortiz, MI [1 ]
Viguri, JR [1 ]
Renedo, MJ [1 ]
Fernandez, J [1 ]
Irabien, JA [1 ]
机构
[1] UNIV CANTABRIA,ETSII & T,DEPT QUIM,SANTANDER 39005,SPAIN
关键词
Ca(OH)(2)/fly-ash sorbents; desulfurization yield; thermogravimetric characterization;
D O I
10.1016/0040-6031(96)02930-9
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work reports the thermogravimetric characterization of the solid products resulting from the low temperature reaction between SO2 and mixed solids containing hydrated mixtures of calcium hydroxide and fly-ashes. The latter sorbents were obtained after a pressurized hydration procedure of coal fly-ashes and commercial calcium hydroxide following a factorial design of the experiments. The analysis of the TG curves performed in a high temperature thermobalance allowed calculation of yield of the desulfurization reaction expressed as mol SO2/mol Ca, a parameter needed for the design and optimization of desulfurization processes.
引用
收藏
页码:173 / 185
页数:13
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