Two Si-Si double bonds connected by a phenylene bridge

被引：89

作者：

Bejan, Iulia ^{[1
]}

Scheschkewitz, David ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 30期

关键词：

conjugation; disilene; double bonds; Group; 14; elements; silicon;

D O I：

10.1002/anie.200701744

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Electronic communication between two Si-Si double bonds is enabled by a phenylene linkage and expressed in a large red shift of the longest-wavelength UV/Vis absorptions of deep red tetrasiladiene 1 compared to yellow phenyldisilene 2. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5783 / 5786

页数：4

共 48 条

[1] An unsaturated α,ω-dianionic oligosilane [J].

Abersfelder, K ;

Güclü, D ;

Scheschkewitz, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1643-1645

[2]

ABERSFELDER K, 2006, ANGEW CHEM, V118, P1673

[3]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[4]

BEJAN I, 2007, ANGEW CHEM, V119, P3413

[5] Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides [J].

Bejan, Iulia ;

Gueclue, Denis ;

Inoue, Shigeyoshi ;

Ichinohe, Masaaki ;

Sekiguchi, Akira ;

Scheschkewitz, David .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (18) :3349-3352

[6] THE PREPARATION AND REACTIONS OF TRIPHENYLSILYLPOTASSIUM [J].

BENKESER, RA ;

SEVERSON, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (04) :1424-1427

[7] THE REACTION OF TRIPHENYLSILYLPOTASSIUM WITH ORGANIC HALIDES, A CASE OF HALOGEN-METAL INTERCONVERSION [J].

BROOK, AG ;

WOLFE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (06) :1431-1437

[8] Charge transport in organic semiconductors [J].

Coropceanu, Veaceslav ;

Cornil, Jerome ;

da Silva Filho, Demetrio A. ;

Olivier, Yoann ;

Silbey, Robert ;

Bredas, Jean-Luc .

CHEMICAL REVIEWS, 2007, 107 (04) :926-952

[9]

FRISCH MJ, 2003, GAUSSIAN 98 G03 REVI

[10]

Glendening E. D., 2001, Theoretical Chemistry Institute

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