Ionic hydrogenation of acylferrocenes using zinc borohydride: An efficient, mild method for the preparation of alkylferrocenes

被引：10

作者：

Bhattacharyya, S

机构：

[1] Department of Chemistry, Vijoygarh College

[2] Department of Chemistry, University of Mississippi, University

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 03期

关键词：

D O I：

10.1021/om950751n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An effective mild procedure for the reductive deoxygenation of alpha-ferrocenyl aldehydes, ketones, and alcohols into the corresponding alkylferrocenes is described using a combination of zinc borohydride and zinc chloride. This is the first example of such reactivity of zinc borohydride. The present method allows the synthesis of alkylferrocenes bearing terminally functionalized pendant chains.

引用

页码：1065 / 1066

页数：2

共 48 条

[1] NEW POLYAZA AND POLYAMMONIUM FERROCENE MACROCYCLIC LIGANDS THAT COMPLEX AND ELECTROCHEMICALLY RECOGNIZE TRANSITION-METAL CATIONS AND PHOSPHATE ANIONS IN WATER [J].