Polarization phenomena at the water/o-nitrophenyl octyl ether interface .1. Evaluation of the standard Gibbs energies of ion transfer from the solubility and voltammetric measurements

被引：73

作者：

Samec, Z

Langmaier, J

Trojanek, A

机构：

[1] J. Heyrousky Inst. of Phys. Chem., Acad. of Sci. of the Czech Republic, 182 23 Prague 8

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 409卷 / 1-2期

关键词：

polarization; water/o-nitrophenyl octyl ether interface;

D O I：

10.1016/0022-0728(95)04382-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Standard Gibbs energies of ion transfer from water to o-nitrophenyl octyl ether are evaluated for a series of ions from voltammetric and solubility measurements by using the tetraphenylarsonium tetraphenylborate hypothesis. Thermodynamic scales derived from these measurements are consistent with each other and with analogous scales for ion transfer to nitrobenzene and 1,2-dichloroethane.

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页码：1 / 7

页数：7

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