Permethylated electron-reservoir sandwich complexes as references for the determination of redox potentials. Suggestion of a new redox scale

被引：128

作者：

Ruiz, J ^{[1
]}

Astruc, D ^{[1
]}

机构：

[1] Univ Bordeaux 1, Chim Organ & Organomet Lab, CNRS, UMR 5802, F-33405 Talence, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1998年 / 1卷 / 01期

关键词：

electron-reservoir sandwiches; redox references; electrochemical scale;

D O I：

10.1016/S1251-8069(97)86255-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The difference between the redox potentials of decamethylferrocene (FeCp2*), decamethylcobalticinium (CoCp2*)(+) and iron-pentamethylcyclopentadienyl-hexamethylbenzene (FeCp*C6Me6)(+ )is shown not to depend on the solvent and anion of the supporting electrolyte whereas ferrocene, whose redox potential is solvent dependent, does not fit in this series. Suggestions are made concerning the possible use of the three permethylated complexes as reliable references for the determination of redox potentials, and a redox scale versus decamethylferrocene is proposed.

引用

页码：21 / 27

页数：7

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