Synthesis of high molecular weight poly(4,4′-bisphenylene vinylene) and poly(2,6-naphthalene vinylene) via a non-ionic precursor route

被引:10
作者
Van Der Borght, M [1 ]
Vanderzande, D [1 ]
Gelan, J [1 ]
机构
[1] Univ Limburg, Lab Organ & Polymer Chem, Inst Mat Res, B-3590 Diepenbeek, Belgium
关键词
poly(arylene vinylene)s; synthesis; characterisation;
D O I
10.1016/S0032-3861(97)10129-X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In previous work a new non-ionic precursor route has been developed. This new route makes it possible to polymerise monomers which possess enlarged aromatic systems. High molecular weight poly(4,4'-bisphenylene vinylene) (7a) and poly(2,6-naphthalene vinylene) (7b) were synthesised. The synthesis of the monomers, the precursor polymer and the conjugated polymers is discussed together with their characterisation. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4171 / 4174
页数:4
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