1,5-enyne metathesis

被引：53

作者：

Debleds, Olivier ^{[1
]}

Campagne, Jean-Marc ^{[1
]}

机构：

[1] Ecole Normale Super Chime Montpellier, Inst Charles Gerhardt Montpellier, F-34296 Montpellier, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期

关键词：

D O I：

10.1021/ja0780986

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enyne metathesis reactions on 1,5-enyne substrates are described, using Grubbs-Hoveyda II catalyst and under microwave irradiation: Cyclobutenes have been obtained in low to fair yields (19-58%).

引用

页码：1562 / +

页数：3

共 52 条

[1] The behavior of 1,n-enynes in the presence of transition metals [J].

Aubert, C ;

Buisine, O ;

Malacria, M .

CHEMICAL REVIEWS, 2002, 102 (03) :813-834

[2] Living ring-opening metathesis polymerization [J].

Bielawski, Christopher W. ;

Grubbs, Robert H. .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) :1-29

[3] Platinum(II) chloride catalyzed cycloisomerizations of 1,5-enynes [J].

Blaszykowski, Christophe ;

Harrak, Youssef ;

Brancour, Celia ;

Nakama, Kimitaka ;

Dhimane, Anne-Lise ;

Fensterbank, Louis ;

Malacria, Max .

SYNTHESIS-STUTTGART, 2007, 13 (13) :2037-2049

[4] Electrophilic activation and cycloisomerization of enynes: A new route to functional cyclopropanes [J].

Bruneau, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (16) :2328-2334

[5] Gold(I)-catalyzed 5-endo hydroxy- and alkoxycyclization of 1,5-enynes:: Efficient access to functionalized cyclopentenes [J].

Buzas, Andrea K. ;

Istrate, Florin M. ;

Gagosz, Fabien .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (07) :1141-1144

[6] Skeletal reorganization of enynes to 1-vinylcycloalkenes catalyzed by GaCl3 [J].

Chatani, N ;

Inoue, H ;

Kotsuma, T ;

Murai, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (35) :10294-10295

[7] A general model for selectivity in olefin cross metathesis [J].

Chatterjee, AK ;

Choi, TL ;

Sanders, DP ;

Grubbs, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11360-11370

[8] Formation of medium-ring heterocycles by diene and enyne metathesis [J].

Chattopadhyay, Shital K. ;

Karmakar, Swastik ;

Biswas, Titas ;

Majumdar, K. C. ;

Rahaman, H. ;

Roy, B. .

TETRAHEDRON, 2007, 63 (19) :3919-3952

[9]

COOKSON RC, 1962, TETRAHEDRON LETT, P615

[10] Diastereoselective gold-catalyzed cycloisomerizations of ene-ynamides [J].

Couty, Sylvain ;

Meyer, Christophe ;

Cossy, Janine .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (40) :6726-6730

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