A molecular logic gate

被引:114
作者
Kompa, KL [1 ]
Levine, RD [1 ]
机构
[1] Max Planck Inst Quantum Opt, D-85740 Garching, Germany
关键词
D O I
10.1073/pnas.98.2.410
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We propose a scheme for molecule-based information processing by combining well-studied spectroscopic techniques and recent results from chemical dynamics. Specifically it is discussed how optical transitions in single molecules can be used to rapidly perform classical (Boolean) logical operations. In the proposed way, a restricted number of states in a single molecule can act as a logical gate equivalent to at least two switches. it is argued that the four-level scheme can also be used to produce gain, because it allows an inversion, and not only a switching ability. The proposed scheme is quantum mechanical in that it takes advantage of the discrete nature of the energy revers but we here discuss the temporal evolution, with the use of the populations only. On a longer time range we suggest that the same scheme could be extended to perform quantum logic, and a tentative suggestion, based on an available experiment, is discussed. We believe that the pumping can provide a partial proof of principle, although this and similar experiments were not interpreted thus far in our terms.
引用
收藏
页码:410 / 414
页数:5
相关论文
共 36 条
  • [1] ASHFOLD MNR, 1994, ANNU REV PHYS CHEM, V45, P57, DOI 10.1146/annurev.physchem.45.1.57
  • [2] Switching of pseudorotaxanes and catenanes incorporating a tetrathiafulvalene unit by redox and chemical inputs
    Balzani, V
    Credi, A
    Mattersteig, G
    Matthews, OA
    Raymo, FM
    Stoddart, JF
    Venturi, M
    White, AJP
    Williams, DJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (07) : 1924 - 1936
  • [3] COHERENT VIBRATIONAL SPECTROSCOPY OF BARRIER DESCENT DYNAMICS
    BENNUN, M
    LEVINE, RD
    [J]. CHEMICAL PHYSICS LETTERS, 1993, 203 (5-6) : 450 - 456
  • [4] Coherent population transfer among quantum states of atoms and molecules
    Bergmann, K
    Theuer, H
    Shore, BW
    [J]. REVIEWS OF MODERN PHYSICS, 1998, 70 (03) : 1003 - 1025
  • [5] Vibrational coherence in ultrafast excited state proton transfer
    Chudoba, C
    Riedle, E
    Pfeiffer, M
    Elsaesser, T
    [J]. CHEMICAL PHYSICS LETTERS, 1996, 263 (05) : 622 - 628
  • [6] A [2]catenane-based solid state electronically reconfigurable switch
    Collier, CP
    Mattersteig, G
    Wong, EW
    Luo, Y
    Beverly, K
    Sampaio, J
    Raymo, FM
    Stoddart, JF
    Heath, JR
    [J]. SCIENCE, 2000, 289 (5482) : 1172 - 1175
  • [7] Electronically configurable molecular-based logic gates
    Collier, CP
    Wong, EW
    Belohradsky, M
    Raymo, FM
    Stoddart, JF
    Kuekes, PJ
    Williams, RS
    Heath, JR
    [J]. SCIENCE, 1999, 285 (5426) : 391 - 394
  • [8] Logic operations at the molecular level. An XOR gate based on a molecular machine
    Credi, A
    Balzani, V
    Langford, SJ
    Stoddart, JF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) : 2679 - 2681
  • [9] de Silva AP, 2000, J AM CHEM SOC, V122, P3965
  • [10] Integration of logic functions and sequential operation of gates at the molecular-scale
    de Silva, AP
    Dixon, IM
    Gunaratne, HQN
    Gunnlaugsson, T
    Maxwell, PRS
    Rice, TE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (06) : 1393 - 1394