Selective complexation of Li+ in water at neutral pH using a self-assembled ionophore

被引：63

作者：

Grote, Z ^{[1
]}

Lehaire, ML ^{[1
]}

Scopelliti, R ^{[1
]}

Severin, K ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chim Mol & Biol, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 45期

关键词：

D O I：

10.1021/ja036621k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trinuclear metallamacrocycle was obtained by assembly of a tridentate ligand and a ruthenium complex in water at neutral pH. The complex acts as a potent ionophore for lithium ions with a Li+/Na+ selectivity of 10000:1. Copyright © 2003 American Chemical Society.

引用

页码：13638 / 13639

页数：2

共 21 条

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