Synthesis of linear and hyperbranched tetrazine-based polyhetarylene assemblies with high nitrogen content

被引：22

作者：

Sagot, E. ^{[1
]}

Le Roux, A. ^{[1
]}

Soulivet, C. ^{[1
]}

Pasquinet, E. ^{[1
]}

Poullain, D. ^{[1
]}

Girard, E. ^{[1
]}

Palmas, P. ^{[1
]}

机构：

[1] CEA Le Ripault, F-37260 Montpellier, France

来源：

TETRAHEDRON | 2007年 / 63卷 / 45期

关键词：

nitrogen heterocycles; tetrazine; polymerization; microwaves;

D O I：

10.1016/j.tet.2007.07.097

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of polyhetarylenes containing exclusively s-tetrazine and another nitrogen heterocycle (pyridine or s-triazine) is described. The key step involved the polymerization of a suitable di- or triamidrazone, leading to a linear or hyperbranched dihydro-tetrazine-based assembly, respectively. The triazinylenetetrazinylene material stands as one of the most nitrogenated polymers ever described. (c) 2007 Elsevier Ltd. All rights reserved.

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页码：11189 / 11194

页数：6

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