Fibers and wires in organogels from low-mass compounds: Typical structural and rheological properties

被引:49
作者
Terech, P [1 ]
机构
[1] Univ Grenoble 1, UMR 5819, CEA,CEA Grenoble, CNRS,Lab Phys Chim Mol,Dept Rech Fondamentale Mat, F-38054 Grenoble 09, France
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1998年 / 102卷 / 11期
关键词
electron microscopy; gels; micelles; neutron scattering; rheology;
D O I
10.1002/bbpc.19981021124
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An overview is given of the special class of thermoreversible organogels and jellies formed with low-mass compounds. Two distinct rheological behaviors can characterize these binary systems: (1) viscoelastic liquids which develop an elasticity over short times, (2) viscoelastic solids which are constituted on long-lived 3-d networks at a temperature T in the gel domain of the phase diagram. Entangled, breakable giant micelles (molecular wires) are opposed to fibers interconnected through crystalline-like microdomains. Certain thermal and rheological properties are presented as well as the detailed structural context at different scales of the fibrillar networks. A brief review of the different chemical classes of organogelators illustrates the growing development in the field. The class of viscoelastic liquids (jellies) is illustrated with the special category of monomolecular organometallic wires.
引用
收藏
页码:1630 / 1643
页数:14
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