Homogeneous Synthesis and Characterization of Cellulose Acetate Butyrate (CAB) in 1-Allyl-3-Methylimidazolium Chloride (AmimCl) Ionic Liquid

被引：61

作者：

Cao, Yan ^{[1
]}

Li, Huiquan ^{[1
]}

Zhang, Jun ^{[2
]}

机构：

[1] Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc Engn, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, Key Lab Engn Plast KLEP, Beijing 100190, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2011年 / 50卷 / 13期

基金：

美国国家科学基金会;

关键词：

1-N-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE; CORNHUSK CELLULOSE; EFFICIENT; ACETYLATION; ACYLATION; SOLVENT; TEMPERATURE; DERIVATIVES; ESTERS; WATER;

D O I：

10.1021/ie2004362

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Cellulose acetate butyrate (CAB) with butyryl content of 6-47 wt % was homogeneously synthesized in 1-allyl-3-methylimidazolium chloride (AmimCl) in a single step without using any catalysts. The effects of different acylating agents (acetic anhydride and butyric anhydride) addition methods and reaction conditions on the acyl content of CABs were investigated. Synthesized CABs were characterized by FTIR, NMR, solubility, and thermal analysis. The acylating agents addition method influences the butyryl content, substituent distribution within the anhydroglucose units (AGU), and the properties of CAB. The CAB obtained with butyryl content greater than 38% is completely soluble in 2-methyl-ethyl ketone, 1,2-dichloromethane, ethyl acetate, and butyl acetate. After the mix-acylation, AmimCl can be easily recycled and reused. This study provides a novel way for the dean production of CAB under mild conditions for future industrial applications.

引用

页码：7808 / 7814

页数：7

共 38 条

[1] Studies on the homogeneous acetylation of cellulose in the novel solvent dimethyl sulfoxide/tetrabutylammonium fluoride trihydrate [J].

Ass, BAP ;

Frollini, E ;

Heinze, T .

MACROMOLECULAR BIOSCIENCE, 2004, 4 (11) :1008-1013

[2] Acylation and carbanilation of cellulose in ionic liquids [J].

Barthel, S ;

Heinze, T .

GREEN CHEMISTRY, 2006, 8 (03) :301-306

[3]

BATZER H, 1981, POLYM BULL, V5, P585

[4]

Cai L, BOT 2021 ANN M BOT S

[5]

Cao Y, 2008, CHEM J CHINESE U, V29, P2115

[6] Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl) [J].

Cao, Yan ;

Wu, Jin ;

Meng, Tao ;

Zhang, Jun ;

He, Jiasong ;

Li, Huiquan ;

Zhang, Yi .

CARBOHYDRATE POLYMERS, 2007, 69 (04) :665-672

[7] Structure and Properties of Novel Regenerated Cellulose Films Prepared from Cornhusk Cellulose in Room Temperature Ionic Liquids [J].

Cao, Yan ;

Li, Huiquan ;

Zhang, Yi ;

Zhang, Jun ;

He, Jiasong .

JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (01) :547-554

[8] SYNTHESIS AND PROPERTIES OF CELLULOSE ACETOACETATES [J].

EDGAR, KJ ;

ARNOLD, KM ;

BLOUNT, WW ;

LAWNICZAK, JE ;

LOWMAN, DW .

MACROMOLECULES, 1995, 28 (12) :4122-4128

[9]

El Seoud OA, 2000, MACROMOL CHEM PHYSIC, V201, P882, DOI 10.1002/(SICI)1521-3935(20000501)201:8<882::AID-MACP882>3.3.CO

[10]

2-9

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