Kinetics and mechanism of nucleophilic addition to nitric oxide: Secondary amine diazeniumdiolation

被引：11

作者：

Bohle, D. Scott ^{[1
]}

Smith, Kamilah N. ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 10期

关键词：

D O I：

10.1021/ic800027m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

kinetics of nitric oxide (NO) addition to dipropylamine and pyrrolidine are determined for a range of solvents and NO pressures. A new isobaric technique is utilized to determine the order of NO, and the kinetics are shown to conform to reactions which are either mono- or bimolecular in NO depending upon the conditions. The mechanism is interpreted in terms of competitive addition of amine to either NO or its dimer.

引用

页码：3925 / 3927

页数：3

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