Mn2(CO)6(μ-CO)(μ-S2):: The simplest disulfide of manganese carbonyl

被引：36

作者：

Adams, RD ^{[1
]}

Kwon, OS ^{[1
]}

Smith, MD ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 21期

关键词：

D O I：

10.1021/ic010619h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new disulfide Mn2(CO)6(μ-CO)(μ-S2), 1, has been obtained from the reaction of Mn2(CO)9(NCMe) with thiirane. Compound 1 contains two Mn(CO)3 groups joined by a Mn-Mn bond, a bridging disulfido ligand, and one bridging CO ligand. Compound 1 condenses upon reaction with CO to yield Mn4S4(CO)15, 2, but yields the tetramanganese disulfide Mn4S2(CO)15(PMe2-Ph)2, 4, and S=PMe2Ph in reaction with PMe2Ph.

引用

页码：5322 / 5323

页数：2

共 17 条

[1] THE SYNTHESIS, STRUCTURES, BONDING AND UNUSUAL REACTIVITY OF SULFIDO OSMIUM CARBONYL CLUSTER COMPOUNDS [J].

ADAMS, RD .

POLYHEDRON, 1985, 4 (12) :2003-2025

[2] Iron-sulfur clusters: Nature's modular, multipurpose structures [J].

Beinert, H ;

Holm, RH ;

Munck, E .

SCIENCE, 1997, 277 (5326) :653-659

[3] REDETERMINATION OF THE CRYSTAL-STRUCTURE OF DIMANGANESE DECACARBONYL AND DETERMINATION OF THE CRYSTAL-STRUCTURE OF DIRHENIUM DECACARBONYL - REVISED VALUES FOR THE MN-MN AND RE-RE BOND LENGTHS IN MN2(CO)10 AND RE2(CO)10 [J].

CHURCHILL, MR ;

AMOH, KN ;

WASSERMAN, HJ .

INORGANIC CHEMISTRY, 1981, 20 (05) :1609-1611

[4] USE OF PREASSEMBLED FE/S AND FE/MO/S CLUSTERS IN THE STEPWISE SYNTHESIS OF POTENTIAL ANALOGS FOR THE FE/MO/S SITE IN NITROGENASE [J].

COUCOUVANIS, D .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (01) :1-8

[5]

ERMENKO IL, 1994, J ORGANOMET CHEM, V471, P123

[6] Synthesis and reactivities at cubane-type sulfido clusters containing noble metals [J].

Hidai, M ;

Kuwata, S ;

Mizobe, Y .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (01) :46-52

[7] METALLCARBONYLE .94. ZUR KENNTNIS DER EISENCARBONYLCHALKOGENIDE [J].

HIEBER, W ;

GRUBER, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1958, 296 (1-6) :91-103

[8]

Holm R. H., 1985, MOLYBDENUM ENZYMES

[9] [1:3] Site-differentiated and sulfide-bridged cubane clusters in chemistry and biology [J].

Holm, RH .

PURE AND APPLIED CHEMISTRY, 1998, 70 (04) :931-938

[10] TRINUCLEAR CUBOIDAL AND HETEROMETALLIC CUBANE-TYPE IRON-SULFUR CLUSTERS - NEW STRUCTURAL AND REACTIVITY THEMES IN CHEMISTRY AND BIOLOGY [J].

HOLM, RH .

ADVANCES IN INORGANIC CHEMISTRY, 1992, 38 :1-71

← 1 2 →