Electrochemical synthesis of poly(paraphenylene vinylene) films

被引：21

作者：

Damlin, P ^{[1
]}

Kvarnström, C ^{[1
]}

Ivaska, A ^{[1
]}

机构：

[1] Abo Akad Univ, Analyt Chem Lab, FIN-20500 Turku, Finland

来源：

ELECTROCHIMICA ACTA | 1999年 / 44卷 / 12期

关键词：

poly(p-phenylene vinylene); electrochemical reduction polymerization; electrochemical doping; in situ conductivity; FTIR;

D O I：

10.1016/S0013-4686(98)00301-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Poly(paraphenylene vinylene) was prepared by electrochemical reduction of alpha,alpha,alpha',alpha'-tetrabromo-p-xylene. The effect of different parameters on the quality of the formed polymer film was studied: monomer material, supporting electrolyte, electrode material, polymerization potential and the preparation procedure. The films polymerized in different electrolyte solutions were studied by sweep electron microscopy (SEM), cyclic voltammetry (CV) and with in situ conductometry measurements. Energy dispersive X-ray analysis (EDXA), dispersive Raman spectroscopy and Fourier transform infrared (FTIR) spectroscopy techniques were used to study the structure of the formed polymer films. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1919 / 1931

页数：13

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