Interpenetrating and non-interpenetrating 3-dimensional coordination polymer frameworks from multiple building blocks

被引：13

作者：

Bradshaw, D ^{[1
]}

Rosseinsky, MJ ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

SOLID STATE SCIENCES | 2005年 / 7卷 / 12期

关键词：

D O I：

10.1016/j.solidstatesciences.2005.04.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Co(NO3)(2)center dot 6H(2)O with the multidentate ligands benzene-1,3,5-tricarboxylate (btc) and the flexible bipyridyl ligand 1,2-bis(4-pyridyl)ethane (bpe) affords the 3-dimensional coordination polymers [Co-3(btc)(2)(bpe)(3)(eg)(2)](.)(guests) 1, where eg = ethylene glycol, and [Co-2(Hbtc)(2)(bpe)(2)](.)(bpe) 2. Both phases are comprised of infinite metal-carboxylate dimer chains, linked into 2-dimensional sheets by the bpe ligands. These sheets are further linked to adjacent sheets through covalent interactions, 1, or through hydrogen-bonding interactions, 2, to yield the 3-dimensional structures. Phase 1 exhibits solvent filled 1-dimensional pores, whereas 2 is triply-interpenetrated to form a dense solid array. (c) 2005 Elsevier SAS. All rights reserved.

引用

页码：1522 / 1532

页数：11

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