A tetracarboxylatobenzene-bridged binuclear copper(II) complex

被引：16

作者：

Chen, W ^{[1
]}

Tioh, NH ^{[1
]}

Zu, JZ ^{[1
]}

Xu, Z ^{[1
]}

You, XZ ^{[1
]}

机构：

[1] NANJING UNIV,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195010444

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetracarboxylatobenzene tetraanion in mu-(1,2,4,5-benzenetetracarboxylato-O-1:O-4)bis[aqua(4-azaheptane- 1,7-diamine-N,N',N '')copper(II)] octahydrate, [{Cu-(C6H17N3)(H2O)}(2)(mu-C10H2O8)].8H(2)O, bridges two N,N',N ''-chelated aquacopper entities in a monodentate manner to give rise to square-pyramidal coordination at the metal centres. Hydrogen bonding involving the three N atoms, the four carboxyl O atoms and the five water molecules gives rise to a three-dimensional network structure.

引用

页码：43 / 45

页数：3

共 10 条

[1] EXPERIMENTAL AND QUANTUM-CHEMICAL INVESTIGATION OF THE MAGNETIC EXCHANGE MECHANISM IN A SERIES OF (MU-TEREPHTHALATO)BIS[(POLYAMINE)COPPER(II)] COMPLEXES [J].

BAKALBASSIS, EG ;

MROZINSKI, J ;

TSIPIS, CA .

INORGANIC CHEMISTRY, 1986, 25 (20) :3684-3690

[2] MODERATELY STRONG INTRAMOLECULAR MAGNETIC EXCHANGE INTERACTION BETWEEN THE COPPER(II) IONS SEPARATED BY 11.25 A IN [L2CU2(OH2)2(MU-TEREPHTHALATO)](CLO4)2 (L = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE) [J].

CHAUDHURI, P ;

ODER, K ;

WIEGHARDT, K ;

GEHRING, S ;

HAASE, W ;

NUBER, B ;

WEISS, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) :3657-3658

[3]

FAIR CK, 1990, MOLEN INTERACTIVE IN

[4] BINUCLEAR DICYCLOPENTADIENYLTITANIUM(III) COMPLEXES - MAGNETIC EXCHANGE INTERACTIONS PROPAGATED BY UNSATURATED AND AROMATIC DICARBOXYLATE DIANIONS [J].

FRANCESCONI, LC ;

CORBIN, DR ;

CLAUSS, AW ;

HENDRICKSON, DN ;

STUCKY, GD .

INORGANIC CHEMISTRY, 1981, 20 (07) :2078-2083

[5] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

[6]

Sheldrick G. M., 1985, SHELXS86 PROGRAM SOL

[7]

SHELDRICK GM, 1993, SHELXL93 PROGRAM REF

[8]

SHELDRICK GM, 1991, SHELXTL PLUS

[9] INTERACTION BETWEEN COPPER(II) IONS SEPARATED BY 7.6 A - CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF (MU-IODANILATO)BIS[(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)COPPER(II)] DIPERCHLORATE [J].

TINTI, F ;

VERDAGUER, M ;

KAHN, O ;

SAVARIAULT, JM .

INORGANIC CHEMISTRY, 1987, 26 (15) :2380-2384

[10]

1988, CAD4 VAX PC FORTRAN

← 1 →