Inverted Polymer Solar Cells Integrated with a Low-Temperature-Annealed Sol-Gel-Derived ZnO Film as an Electron Transport Layer

被引：1449

作者：

Sun, Yanming ^{[1
]}

Seo, Jung Hwa ^{[1
]}

Takacs, Christopher J. ^{[1
]}

Seifter, Jason ^{[1
]}

Heeger, Alan J. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 14期

关键词：

RAY PHOTOELECTRON-SPECTROSCOPY; PHOTOVOLTAIC CELLS; EFFICIENT; DEGRADATION; NETWORK;

D O I：

10.1002/adma.201004301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly efficient and air-stable inverted polymer solar cells are fabricated with a poly(2,7-carbazole) derivative (PCDTBT):fullerene derivative (PC70BM) active layer. Low-temperature-annealed sol-gel-derived zinc oxide (ZnO) and molybdenum oxide films are selected as the electron and hole transporting layers, respectively. Power conversion efficiency (PCE) of 6.3% is demonstrated, which is the highest reported to date for inverted polymer solar cells.

引用

页码：1679 / +

页数：6

共 38 条

[1] Device physics of polymer:fullerene bulk heterojunction solar cells [J].

Blom, Paul W. M. ;

Mihailetchi, Valentin D. ;

Koster, L. Jan Anton ;

Markov, Denis E. .

ADVANCED MATERIALS, 2007, 19 (12) :1551-1566

[2] Toward a rational design of poly(2,7-carbazole) derivatives for solar cells [J].

Blouin, Nicolas ;

Michaud, Alexandre ;

Gendron, David ;

Wakim, Salem ;

Blair, Emily ;

Neagu-Plesu, Rodica ;

Belletete, Michel ;

Durocher, Gilles ;

Tao, Ye ;

Leclerc, Mario .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) :732-742

[3] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Brabec, Christoph J. ;

Gowrisanker, Srinivas ;

Halls, Jonathan J. M. ;

Laird, Darin ;

Jia, Shijun ;

Williams, Shawn P. .

ADVANCED MATERIALS, 2010, 22 (34) :3839-3856

[4] Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].

Chen, Li-Min ;

Hong, Ziruo ;

Li, Gang ;

Yang, Yang .

ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449

[5] X-ray photoelectron spectroscopy and auger electron spectroscopy studies of Al-doped ZnO films [J].

Chen, M ;

Wang, X ;

Yu, YH ;

Pei, ZL ;

Bai, XD ;

Sun, C ;

Huang, RF ;

Wen, LS .

APPLIED SURFACE SCIENCE, 2000, 158 (1-2) :134-140

[6] A Thermally Stable Semiconducting Polymer [J].

Cho, Shinuk ;

Seo, Jung Hwa ;

Park, Sung Heum ;

Beaupre, Serge ;

Leclerc, Mario ;

Heeger, Alan J. .

ADVANCED MATERIALS, 2010, 22 (11) :1253-+

[7] Stability of the interface between indium-tin-oxide and poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) in polymer light-emitting diodes [J].

de Jong, MP ;

van IJzendoorn, LJ ;

de Voigt, MJA .

APPLIED PHYSICS LETTERS, 2000, 77 (14) :2255-2257

[8] Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].

Dennler, Gilles ;

Scharber, Markus C. ;

Brabec, Christoph J. .

ADVANCED MATERIALS, 2009, 21 (13) :1323-1338

[9] The use of ZnO as optical spacer in polymer solar cells: Theoretical and experimental study [J].

Gilot, Jan ;

Barbu, Ionut ;

Wienk, Martijn M. ;

Janssen, Rene A. J. .

APPLIED PHYSICS LETTERS, 2007, 91 (11)

[10] Conjugated polymer-based organic solar cells [J].

Guenes, Serap ;

Neugebauer, Helmut ;

Sariciftci, Niyazi Serdar .

CHEMICAL REVIEWS, 2007, 107 (04) :1324-1338

← 1 2 3 4 →