Efficient syntheses of optically active 2-arylalkanoic acids.

被引：18

作者：

Beaulieu, C ^{[1
]}

Spino, C ^{[1
]}

机构：

[1] Univ Sherbrooke, Dept Chim, Sherbrooke, PQ J1K 2R1, Canada

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 09期

关键词：

asymmetric reactions; substitution; pesticides; antiinflammatory compounds;

D O I：

10.1016/S0040-4039(99)00055-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly enantioselective synthesis of 2-arylpropanoic acid was achieved, using a new developed methodology of cuprate addition to chiral carbonates derived from menthone. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1637 / 1640

页数：4

共 9 条

[1] RESOLUTION AND CONFIGURATION OF ALPHA-SUBSTITUTED PHENYLACETIC ACIDS
AARON, C
DULL, D
SCHMIEGE.JL
JAEGER, D
OHASHI, Y
MOSHER, HS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (09) : 2797 - &
[2] PURE ENANTIOMERS OF 2-ARYLPROPIONIC ACIDS - TOOLS IN PAIN RESEARCH AND IMPROVED DRUGS IN RHEUMATOLOGY
BRUNE, K
GEISSLINGER, G
MENZELSOGLOWEK, S
[J]. JOURNAL OF CLINICAL PHARMACOLOGY, 1992, 32 (10) : 944 - 952
[3] Corey E.J., 1972, TETRAHEDRON LETT, V13, P3769, DOI DOI 10.1016/S0040-4039(01)94157-7
[4] Davies J. H., 1985, PYRETHROID INSECTICI, P1
[5] GAMMA-DELTA-UNSATURATED CARBONYL-COMPOUNDS AS 4-BUTANOLIDE SYNTHON
HO, TL
[J]. SYNTHETIC COMMUNICATIONS, 1982, 12 (01) : 53 - 56
[6] Lombardino G., 1985, NONSTEROIDAL ANTIINF
[7] ZINC SALT CATALYZED REARRANGEMENT OF ACETALS OF OPTICALLY-ACTIVE ARYL 1-CHLOROETHYL KETONES - SYNTHESIS OF OPTICALLY-ACTIVE 2-ARYLPROPIONIC ACIDS AND ESTERS
PICCOLO, O
SPREAFICO, F
VISENTIN, G
VALOTI, E
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (01) : 10 - 14
[8] RECENT DEVELOPMENTS IN THE SYNTHESIS OF OPTICALLY-ACTIVE ALPHA-ARYLPROPANOIC ACIDS - AN IMPORTANT CLASS OF NONSTEROIDAL ANTIINFLAMMATORY AGENTS
SONAWANE, HR
BELLUR, NS
AHUJA, JR
KULKARNI, DG
[J]. TETRAHEDRON-ASYMMETRY, 1992, 3 (02) : 163 - 192
[9] A practical and highly stereoselective umpolung alternative to the alkylation of chiral enolates
Spino, C
Beaulieu, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) : 11832 - 11833

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